Quantifying the working stroke of tetrathiafulvalene-based electrochemically-driven linear motor-molecules.
نویسندگان
چکیده
A highly constrained [2]rotaxane, constructed in such a way that the tetracationic cyclobis(paraquat-p-phenylene) ring is restricted to reside on a monopyrrolotetrathiafulvalene unit, has been synthesised and characterised. This design allows the deslipping free energy barrier for the tetracationic ring in all three redox states of the rotaxane to be determined.
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ورودعنوان ژورنال:
- Chemical communications
دوره 2 شماره
صفحات -
تاریخ انتشار 2006